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In this episode of The Wine Lab, we explore the science and story of tannins: what they are, where they come from, and why some wines feel silky while others grip your gums.
From the ancient craft of leather tanning to modern barrel aging, we trace how these polyphenolic compounds shape wine’s structure, color, and longevity. We’ll look at how fermentation temperature, pH, and rising alcohol shift what gets extracted from skins and seeds — and how acidity changes the way tannins feel on your palate.
You’ll also learn why black tea gives you the same dry feeling as a young Cabernet, that tannins aren’t probably the cause of wine headaches, and why some white wines have more tannin character than you might think.
So pour a glass, and let’s explore the chemistry of feeling wine.
Astringency – The tactile, drying sensation in the mouth caused by tannins binding to salivary proteins, reducing lubrication. It’s a feeling, not a flavor.
Tannins – Polyphenolic compounds found in grape skins, seeds, stems, and oak. They contribute structure, color stability, and aging potential to wine.
Condensed tannins (Proanthocyanidins) – Tannins naturally present in grapes; built from flavan-3-ols. They shape a wine’s body and mouthfeel.
Hydrolyzable tannins – Tannins derived from oak barrels, composed of gallic or ellagic acid units. They provide antioxidant capacity and subtle structure during aging.
Anthocyanins – Water-soluble pigments in grape skins that give red and purple wines their color. They stabilize when bonded to tannins.
Maceration – The period during fermentation when grape skins and seeds are in contact with the juice, allowing extraction of color, flavor, and tannins.
pH / Acidity – A measure of wine’s acid level. Lower pH (higher acidity) makes tannins feel firmer; higher pH makes them feel softer.
Polymerization – The process where small tannin molecules link into longer chains over time, softening texture and reducing astringency.
Ethanol – The alcohol formed during fermentation. It changes the solubility of phenolics, enhancing seed-tannin extraction but slowing pigment release.
Tribology – The study of friction and lubrication. Used in wine sensory research to explain how tannins affect mouthfeel.
Ellagitannins – Oak-derived tannins that help stabilize color and protect wine from oxidation during barrel aging.
Extended maceration – A winemaking technique where wine remains on skins after fermentation to extract additional tannins and complexity.
Aging – The slow chemical evolution of wine after fermentation. Tannins polymerize and precipitate, softening texture over time.
Bitterness – A taste detected by receptors on the tongue, distinct from astringency (a physical sensation).
Color stability – The persistence of wine color over time, maintained by reactions between tannins and anthocyanins that form more stable pigments.
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